In both his calculations, the gambler used the simplified addition rule. This overlooks the fact that the outcomes he is dealing with are not mutually exclusive; he may get a 6 (or a double 6) in more than one roll. To calculate the true probabilities, we need to use the full addition rule.
In fact, the simplest way to proceed is to calculate the
probability of getting no 6 in four throws. Since the
throws are independent, we can use the simplified
multiplication rule, which tells us that the probability of
getting no 6 in four throws is
= 0.482. Since the
probability of getting at least one 6 covers all the other
outcomes, we can use the subtraction rule to calculate this
probability; it is 1
0.482 = 0.518.
Similarly, we can calculate the probability of getting no
double 6 in 24 throws. Since the probability of not getting a
double 6 in one throw is 35/36, and the throws are
independent, the probability of getting no double 6 in 24
throws is
= 0.509. Again, by the subtraction
rule, the probability of getting at least one double 6 is
1
0.509 = 0.491. This is lower than the probability of
getting at least one 6 in four throws, as the gambler had
noticed.
Thinking is like loving or dying. Each of us must do it for himself.

Josiah Royce